Koliko plamenogasitelji menjaju stabilnost jednobaznih baruta?
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Jul 17, 2026
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Mladen Bugarčić
http://orcid.org/0000-0002-6119-4414
Janko Živanić
Lazar Lapčević
Aleksandar Jovanović
http://orcid.org/0000-0001-9867-9282
Dimitrije Anđić
http://orcid.org/0009-0001-6824-5202
Anđela Simonović
http://orcid.org/0000-0003-4026-5647
Jovica Nešić
http://orcid.org/0000-0002-0941-2445
http://orcid.org/0000-0002-6119-4414
Janko Živanić
Lazar Lapčević
Aleksandar Jovanović
http://orcid.org/0000-0001-9867-9282
Dimitrije Anđić
http://orcid.org/0009-0001-6824-5202
Anđela Simonović
http://orcid.org/0000-0003-4026-5647
Jovica Nešić
http://orcid.org/0000-0002-0941-2445
Apstrakt
Plamenogasitelji, pojedine kalijumove soli, koriste se kao aditivi radi smanjenja bljeska na ustima cevi. Uticaj se zasniva na inhibiciji postplamenih reakcija, odnosno na vezivanju reaktivnih radikala u gasnoj fazi i usporavanju sekundarnih lančanih reakcija sagorevanja, čime se smanjuje intenzitet vidljivog plamena. Brojni primeri iz prakse, kao i dostupni literaturni podaci, ukazuju da prisustvo kalijum-sulfata u barutnoj masi nepovoljno utiče na hemijsku stabilnost jednobaznih baruta. U ovom radu analiziraće se uticaj sastava barutne mase i tehnološkog postupka prerade na krajnju hemijsku stabilnost tri jednobazna baruta različite namene, NC-151, NC-48 i NCD-27, kojima je zajedničko prisustvo određene količine kalijum-sulfata. Poređenjem njihovog hemijskog sastava, sadržaja stabilizatora i ključnih faza tehnološke obrade biće razmotreno na koji način sastav i procesni parametri utiču na hemijsku stabilnost jednobaznih baruta. Procena hemijske stabilnost biće izražena parametrom Bergmann–Junk, a Dobijeni rezultati su interpretirani u skladu sa dostupnim teorijskim postavkama i specifičnostima proizvodnog procesa, sa ciljem identifikacije ključnih parametara koji utiču na hemijsku stabilnost jednobaznih baruta koji sadrže kalijum sulfat kao plamenogasitelj..
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Kako citirati
BUGARČIĆ, Mladen et al.
Koliko plamenogasitelji menjaju stabilnost jednobaznih baruta?.
Zbornik Međunarodnog kongresa o procesnoj industriji – Procesing, [S.l.], v. 39, n. 1, p. 77-84, july 2026.
Dostupno na: <http://izdanja.smeits.rs/index.php/ptk/article/view/8335>. Datum pristupa: 07 aug. 2026
doi: https://doi.org/10.24094/ptk.026.1.077.
Sekcija
Procesne tehnologije, operacije, aparati i mašine u procesnoj industriji
Reference
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[3] Woodbridge, R. G., Propellent powder. US 1,888,847. 29 December 1931. United States of America.
[4] Woodbridge, R. G., Flashless powder charge. US 2,050,871. 11 August 1936. United States of America.
[5] Katoh, K., Higashi, E., Nakano, K., Ito, S., Wada, Y., Kasamatsu, J., Miya, H., Yamamoto, M., and Wada, Y., Thermal behavior of nitrocellulose with inorganic salts and their mechanistic action. Propellants, Explosives, Pyrotechnics. October 2010. Vol. 35, no. 5, p. 461–467. DOI 10.1002/prep.200900074. 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
[6] Li, W., Wang, B., Zhang, J., Li, S., Xu, W., Liang, J., Fan, W., Ding, Y., Xiao, Z. and Zhou, J., Regulating the Thermal Behavior of Nitrocellulose by Stable Incorporation of a Green Supramolecular Salt. Polymer Degradation and Stability. 1 February 2024. Vol. 220. DOI 10.1016/j.polymdegradstab.2023.110636.
[7] Maksimović, P. V. Tehnologija baruta i eksploziva. Online. 1. Zagreb : Tehnički školski centar JNA, 1968. Available from: https://books.google.rs/books?id=P_doSAAACAAJ
[8] Babushok, V. I., Linteris, G. T., Hoorelbeke, P., Roosendans, D. and Van Wingerden, K., Flame Inhibition by Potassium-Containing Compounds. Combustion Science and Technology. 2 December 2017. Vol. 189, no. 12, p. 2039–2055. DOI 10.1080/00102202.2017.1347162.
[9] Cohen, A. and Decker, L., Chemical mechanism for secondary flash suppression. Symposium (International) on Combustion. Online. 1981. Vol. 18, no. 1, p. 225–231. DOI https://doi.org/10.1016/S0082-0784(81)80027-6.
[10] Chalghoum, F., Tarchoun, A. F., Abdelaziz, A., boukeciat, H., Hanafi, S., Saber, M. W., Chelouche, S., Benziane, M. and Trache, D., Influence of moisture content on the thermal de-composition kinetics of smokeless gunpowders. FirePhysChem. 1 August 2025. Vol. 5, no. 4, p. 313–322. DOI 10.1016/j.fpc.2024.11.003
[11] Rusly, S. N. A., Jamal, S. H., Samsuri, A., Mohd Noor, S. A. and Abdul Rahim, K. S., Sta-bilizer selection and formulation strategies for enhanced stability of single base nitrocellulose propellants: A review. 1 March 2024. KeAi Communications Co.
[12] Djokić, M. M., Bajić, Z. J. and Ignjatović, V. D. Towards the reliable chemical stability test-ing of the single base gunpowder using a microcalorimetry method. Military Technical Couri-er/Vojnotehnicki glasnik. 2024. Vol. 72, no. 3, p. 1395–1413. DOI 10.5937/vojtehg72-51113.
[13] Tomaszewski, W., Cies̈lak, K. and Zygmunt, A., Influence of processing solvents on decom-position of nitrocellulose in smokeless powders studied by heat flow calorimetry. Polymer Deg-radation and Stability. 2015. Vol. 111, p. 169–175. DOI 10.1016/j.polymdegradstab.2014. 11.010.
[14] Wei, R. C., Huang, S. S., Wang, Z., He, Y., Yuen, R. and Wang, J., Estimation on the Safe Storage Temperature of Nitrocellulose with Different Humectants. Propellants, Explosives, Pyro-technics. 1 November 2018. Vol. 43, no. 11, p. 1122–1128. DOI 10.1002/prep.201800149.
[15] Zhang, X., Lei, M., Ren, J., Li, Z., Duan, X., Shen, J. and Pei, C., Influence of solvents on solubility, processability, thermostability, and mechanical properties of nitrocellulose gun propel-lants. Cellulose. 1 February 2025. Vol. 32, no. 3, p. 1539–1556. DOI 10.1007/s10570-025-06377-2.
[16] Rakić, M., Krstović, M., Dimić, M. and Fidanovski, B., Classical methods of Chemical stabil-ity: Comparison of analyses for gunpowders. Scientific Technical Review. 2021. Vol. 71, no. 1, p. 25–29. DOI 10.5937/str2101025r.
[17] Chebbah, M., Tarchoun, A. F., Benaliouche, F., Abdelaziz, A. and Trache, D., Advancing nitrocellulose thermal stability through the incorporation of ion-exchanged ZSM-5 zeolite for en-hanced performance. FirePhysChem. 1 June 2025. Vol. 5, no. 3, p. 209–222. DOI 10.1016/ j.fpc.2024.09.006.
[2] Bret, P. Managing Chemical Expertise: The Laboratories of the French Artillery and the Service des Poudres. In: MACLEOD, Roy and JOHNSON, Jeffrey Allan (eds.), Frontline and Factory: Comparative Perspectives on the Chemical Industry at War, 1914–1924. Online. Dordrecht: Springer Netherlands, 2006. p. 203–219. ISBN 978-1-4020-5490-7.
[3] Woodbridge, R. G., Propellent powder. US 1,888,847. 29 December 1931. United States of America.
[4] Woodbridge, R. G., Flashless powder charge. US 2,050,871. 11 August 1936. United States of America.
[5] Katoh, K., Higashi, E., Nakano, K., Ito, S., Wada, Y., Kasamatsu, J., Miya, H., Yamamoto, M., and Wada, Y., Thermal behavior of nitrocellulose with inorganic salts and their mechanistic action. Propellants, Explosives, Pyrotechnics. October 2010. Vol. 35, no. 5, p. 461–467. DOI 10.1002/prep.200900074. 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
[6] Li, W., Wang, B., Zhang, J., Li, S., Xu, W., Liang, J., Fan, W., Ding, Y., Xiao, Z. and Zhou, J., Regulating the Thermal Behavior of Nitrocellulose by Stable Incorporation of a Green Supramolecular Salt. Polymer Degradation and Stability. 1 February 2024. Vol. 220. DOI 10.1016/j.polymdegradstab.2023.110636.
[7] Maksimović, P. V. Tehnologija baruta i eksploziva. Online. 1. Zagreb : Tehnički školski centar JNA, 1968. Available from: https://books.google.rs/books?id=P_doSAAACAAJ
[8] Babushok, V. I., Linteris, G. T., Hoorelbeke, P., Roosendans, D. and Van Wingerden, K., Flame Inhibition by Potassium-Containing Compounds. Combustion Science and Technology. 2 December 2017. Vol. 189, no. 12, p. 2039–2055. DOI 10.1080/00102202.2017.1347162.
[9] Cohen, A. and Decker, L., Chemical mechanism for secondary flash suppression. Symposium (International) on Combustion. Online. 1981. Vol. 18, no. 1, p. 225–231. DOI https://doi.org/10.1016/S0082-0784(81)80027-6.
[10] Chalghoum, F., Tarchoun, A. F., Abdelaziz, A., boukeciat, H., Hanafi, S., Saber, M. W., Chelouche, S., Benziane, M. and Trache, D., Influence of moisture content on the thermal de-composition kinetics of smokeless gunpowders. FirePhysChem. 1 August 2025. Vol. 5, no. 4, p. 313–322. DOI 10.1016/j.fpc.2024.11.003
[11] Rusly, S. N. A., Jamal, S. H., Samsuri, A., Mohd Noor, S. A. and Abdul Rahim, K. S., Sta-bilizer selection and formulation strategies for enhanced stability of single base nitrocellulose propellants: A review. 1 March 2024. KeAi Communications Co.
[12] Djokić, M. M., Bajić, Z. J. and Ignjatović, V. D. Towards the reliable chemical stability test-ing of the single base gunpowder using a microcalorimetry method. Military Technical Couri-er/Vojnotehnicki glasnik. 2024. Vol. 72, no. 3, p. 1395–1413. DOI 10.5937/vojtehg72-51113.
[13] Tomaszewski, W., Cies̈lak, K. and Zygmunt, A., Influence of processing solvents on decom-position of nitrocellulose in smokeless powders studied by heat flow calorimetry. Polymer Deg-radation and Stability. 2015. Vol. 111, p. 169–175. DOI 10.1016/j.polymdegradstab.2014. 11.010.
[14] Wei, R. C., Huang, S. S., Wang, Z., He, Y., Yuen, R. and Wang, J., Estimation on the Safe Storage Temperature of Nitrocellulose with Different Humectants. Propellants, Explosives, Pyro-technics. 1 November 2018. Vol. 43, no. 11, p. 1122–1128. DOI 10.1002/prep.201800149.
[15] Zhang, X., Lei, M., Ren, J., Li, Z., Duan, X., Shen, J. and Pei, C., Influence of solvents on solubility, processability, thermostability, and mechanical properties of nitrocellulose gun propel-lants. Cellulose. 1 February 2025. Vol. 32, no. 3, p. 1539–1556. DOI 10.1007/s10570-025-06377-2.
[16] Rakić, M., Krstović, M., Dimić, M. and Fidanovski, B., Classical methods of Chemical stabil-ity: Comparison of analyses for gunpowders. Scientific Technical Review. 2021. Vol. 71, no. 1, p. 25–29. DOI 10.5937/str2101025r.
[17] Chebbah, M., Tarchoun, A. F., Benaliouche, F., Abdelaziz, A. and Trache, D., Advancing nitrocellulose thermal stability through the incorporation of ion-exchanged ZSM-5 zeolite for en-hanced performance. FirePhysChem. 1 June 2025. Vol. 5, no. 3, p. 209–222. DOI 10.1016/ j.fpc.2024.09.006.