Perfluoroalkilne i polifluoroalkilne supstance – porodica jedinjenja koja raste
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Poslednjih nekoliko godina predstavljalo je otrežnjenje za mnoge, uključujući širu javnost, kada je reč o problemima povezanim sa sve većim zagađenjem različitim hemikalijama. U žiži interesovanja bile su perfluorovane i polifluorovane supstance (PFAS), koje je OECD redefinisala [1].
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PACHAI, Alexander Cohr.
Perfluoroalkilne i polifluoroalkilne supstance – porodica jedinjenja koja raste.
KGH – Klimatizacija, grejanje, hlađenje, [S.l.], v. 53, n. 4, p. 31-36, nov. 2024.
ISSN 2560-340X.
Dostupno na: <https://izdanja.smeits.rs/index.php/kgh/article/view/8114>. Datum pristupa: 07 dec. 2024
doi: https://doi.org/10.24094/kghc.024.53.1.31.
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Reference
*** Reconciling Terminology of the Universe of Per- and Polyfluoroalkyl Substances: Recommendations and Practical Guidance, OECD Series on Risk Management, 61, OECD Publishing, Paris, 2021
Wang. Z., A. M. Buser, I. T. Cousins, S. Demattio, W. Drost, O. Johansson, K. Ohno, G. Patlewicz, A. M. Richard, G. W. Walker, G. S. White, E. Leinala, A New OECD Definition for Per- and Polyfluoroalkyl Substances, Environmental Science & Technology, 55 (23), 15575-15578, 2021, DOI: 10.1021/acs.est.1c06896
Buck, R. C., J. Franklin, U. Berger, J. M. Conder, I. T. Cousins, P. de Voogt, A. A. Jensen, K. Kannan, S. A. Mabury, S. P. J. van Leeuwen. Perfluoroalkyl and poly-fluoroalkyl substances in the environment: Terminology, classification, and origins, 2011, https://doi.org/10.1002/ieam.258
https://pubs.acs.org/doi/10.1021/acs.est.3c04855
https://en.wikipedia.org/wiki/Fluorine_compounds
https://www.essentialchemicalindustry.org/chemicals/hydrogen-fluoride.html
Pashkevich, D., A. V. Mamaev, Production of hydrogen fluoride by processing fluorine-containing wastes and by-products of modern industries, Peter the Great St Petersburg Polytechnic University, “New Chemical Products” Ltd., Russia
Visscher, P. T., C. W. Culbertson, R. S. Oremland, Degradation of trifluoroacetate in oxic and anoxic sediments, Letters to Nature, Nature, 369, 30 June 1994
IPCC Assessment report 6 https://www.ipcc.ch/report/ar6/wg1/downloads/report/IPCC_AR6_WGI_Chapter07_SM.pdf
Zhang, P., L. Cao, R. Pan, Z. Jiang, K. Qin, Q. Li, A study on the pyrolysis of CHF3. The 9th Asia-Oceania Symposium on Fire Science and Technology, Procedia Engineering, 62, pp. 337–341, 2013
https://eu.usatoday.com/story/news/nation/2024/08/30/pfas-firefighter-gear-ban-massachusetts-connecticut/74946327007/
https://www.statista.com/statistics/1051717/global-fluorspar-production-by-country/
https://chem.libretexts.org/Courses/Mount_Royal_University/Chem_1201/Unit_2._Periodic_Properties_of_the_Elements/2.12%3A_Electronegativity
https://en.wikipedia.org/wiki/Electronegativity
https://www.sciencedirect.com/topics/chemistry/electronegativity
Cho, Y.-S., N. Soyoung, S. Jeong, Y.-S. Kim, Low-cost fabrication of flexible water-repellent film by spray coating of a hydrophobic nanoparticle dispersion, Journal of Dispersion Science and Technology, 41, 10, 2019, http://dx.doi.org/10.1080/01932691.2019.1627883
https://www.scribd.com/document/212369617/Fluorinated-Pharmaceuticals
Shabir, G., A. Saeed, W. Zahid, F. Naseer, Z. Riaz, N. Khalil, N., Muneeba, F. Albericio, Chemistry and Pharmacology of Fluorinated Drugs Approved by the FDA (2016–2022), Pharmaceuticals, 16, 1162, 2023, https://doi.org/10.3390/ ph16081162
Patai’s Chemistry of Functional Groups Modern Fluorine-Containing Agrochemicals https://onlinelibrary.wiley.com/doi/abs/10.1002/9780470682531.pat1013#:~:text=Today%2C%20modern%20fluorine-containing%20agrochemicals%20are%20of%20the%20utmost,the%20food%20supply%20for%20a%20growing%20world%20population.?msockid=02ec270e3493696236cd33ab356f68a3
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7946751/pdf/nihms-1662362.pdf
https://banpfasmanifesto.org/en/, Checked August 18th, 2024
Tang, C., Y. Wang, H. Hong, Unraveling the link between heavy metals, perfluoroalkyl substances and depression: Insights from epidemiological and bioinformatics strategies. Ecotoxicology and Environmental Safety. https://doi.org/10.1016/j.ecoenv.2024.116482
Kim, J. I, B.-N. Kim, Y. A. Lee, C. H. Shin, Y.-C. Hong, L. D. Dossing, G. Hildebrandt, Y.-H. Lim, Association between early-childhood exposure to perfluoroalkyl substances and hyperactivity disorder (ADHD): A prospective cohort study. Science of the Total Environment, 879, 163081, 2023.
Harris, M. H. E. Oken, S. L. Rifas-Shiman, A. M. Calafat, D. C. Bellinger, T. F. Webster, R. F. White, S. K. Sagiv, Prenatal and childhood exposure to per- and polyfluoroalkyl substances (PFAS) and child executive function and behavioral problems. Environmental Research, 202, 111621, 2021, https://doi.org/10.1016/j.envres.2021.111621
Basaly, V., J. Hill, S. W. Bihaqi, E. Marques, A. L. Slitt, N. H. Zawia, Developmental Perfluorooctanesulfonic acid (PFOS) Exposure as a Potential Risk Factor for Late-Onset Alzheimer’s Disease in CD-1 Mice and SH-SY5Y Cells. DOI: 10.1016/j.neuro.2021.06.008
https://data.geus.dk/pure-pdf/GEUS-R_2024-4_web.pdf
https://link.springer.com/article/10.1007/s11356-024-32082-x
https://www.anourishingharvest.com/articles/pfas-and-plants
https://www.cieh.org/ehn/food-safety-integrity/2024/april/pan-uk-data-shows-toxic-pfas-in-uk-fruit-vegetables-and-spices/
https://www.foodandwaterwatch.org/2024/02/08/pfas-sewage-sludge/
https://regionsyddanmark.dk/media/2jhjpev5/clean_unders%C3%B8gelser-af-kystn%C3%A6r-pfas-forurening_syddanske-udviklingspulje-22-52316_rapport-03-10_2023_optimized.pdf
https://www.efsa.europa.eu/en/news/pfas-food-efsa-assesses-risks-and-sets-tolerable-intake
https://cot.food.gov.uk/sites/default/files/2022-10/TOX-2022-53 PFAS further work_Final.pdf
https://cot.food.gov.uk/sites/default/files/2022-10/PFAS final draft statement V2_September 2022_AB_OOS - SW Updated 17-10-22.pdf
https://foedevarestyrelsen.dk/kost-og-foedevarer/foedevaresikkerhed/kemiske-stoffer-og-toksiner/miljoeforureninger-i-foedevarer/pfas/pfas-i-foedevarer
Cappelli, F., Y. A., Bamai, K., Van Hoey, D., Kim, A. Covaci, Occurrence of short- and ultra-short chain PFAS in drinking water from Flanders (Belgium) and implications for human exposure. Environmental Research, 119753, 2024, https://doi.org/10.1016/j.envres.2024.119753
https://www.eea.europa.eu/en/european-zero-pollution-dashboards/indicators/pfas-in-eu-seas
https://mim.dk/nyheder/pressemeddelelser/2023/december/danmark-gaar-foran-i-arbejdet-med-at-begraense-pfas-i-vandmiljoe-og-spildevand
https://havhøst.dk/
https://phys.org/news/2024-04-ocean-propel-pfas.html
https://danskevv.dk/nyheder/pfas-i-havskum-en-kilde-til-forureninger-i-grundvandet/#:~:text=PFAS%20i%20havskum%3A%20En%20kilde%20til%20forureninger%20i,hvor%20fluorstofferne%20udg%C3%B8r%20en%20trussel%20for%20vores%20drikkevand.https://www.food.dtu.dk/newsarchive/2023/01/pfas-fundet-i-oekologiske-aeg
Zheng, G., S.M., Eick, A., Salamova, Elevated Levels of Ultrashort- and Short-Chain Perfluoroalkyl Acids in US Homes and People, Environmental Science & Technology. Environ. Sci. Technol., 57, pp. 15782−15793, 2023, https://pubs.acs.org/10.1021/acs.est.2c06715
Annual European Union greenhouse gas inventory 1990–2021 and inventory report 2023, April 15th, 2023. Submission to the UNFCCC Secretariat, https://www.eea.europa.eu/publications/annual-european-union-greenhouse-gas-2
https://unfccc.int/process-and-meetings/the-paris-agreement
https://www.unep.org/news-and-stories/press-release/nations-must-go-further-current-paris-pledges-or-face-global-warming
https://www.weforum.org/agenda/2023/09/prevent-1-5-degrees-celsius-climate-threshold/
https://www.bbc.com/news/science-environment-68110310
https://www.who.int/news/item/25-03-2014-7-million-premature-deaths-annually-linked-to-air-pollutionhttps://nyheder.tv2.dk/samfund/2022-08-05-her-er-de-15000-steder-der-mistaenkes-for-pfas-forurening
Wang. Z., A. M. Buser, I. T. Cousins, S. Demattio, W. Drost, O. Johansson, K. Ohno, G. Patlewicz, A. M. Richard, G. W. Walker, G. S. White, E. Leinala, A New OECD Definition for Per- and Polyfluoroalkyl Substances, Environmental Science & Technology, 55 (23), 15575-15578, 2021, DOI: 10.1021/acs.est.1c06896
Buck, R. C., J. Franklin, U. Berger, J. M. Conder, I. T. Cousins, P. de Voogt, A. A. Jensen, K. Kannan, S. A. Mabury, S. P. J. van Leeuwen. Perfluoroalkyl and poly-fluoroalkyl substances in the environment: Terminology, classification, and origins, 2011, https://doi.org/10.1002/ieam.258
https://pubs.acs.org/doi/10.1021/acs.est.3c04855
https://en.wikipedia.org/wiki/Fluorine_compounds
https://www.essentialchemicalindustry.org/chemicals/hydrogen-fluoride.html
Pashkevich, D., A. V. Mamaev, Production of hydrogen fluoride by processing fluorine-containing wastes and by-products of modern industries, Peter the Great St Petersburg Polytechnic University, “New Chemical Products” Ltd., Russia
Visscher, P. T., C. W. Culbertson, R. S. Oremland, Degradation of trifluoroacetate in oxic and anoxic sediments, Letters to Nature, Nature, 369, 30 June 1994
IPCC Assessment report 6 https://www.ipcc.ch/report/ar6/wg1/downloads/report/IPCC_AR6_WGI_Chapter07_SM.pdf
Zhang, P., L. Cao, R. Pan, Z. Jiang, K. Qin, Q. Li, A study on the pyrolysis of CHF3. The 9th Asia-Oceania Symposium on Fire Science and Technology, Procedia Engineering, 62, pp. 337–341, 2013
https://eu.usatoday.com/story/news/nation/2024/08/30/pfas-firefighter-gear-ban-massachusetts-connecticut/74946327007/
https://www.statista.com/statistics/1051717/global-fluorspar-production-by-country/
https://chem.libretexts.org/Courses/Mount_Royal_University/Chem_1201/Unit_2._Periodic_Properties_of_the_Elements/2.12%3A_Electronegativity
https://en.wikipedia.org/wiki/Electronegativity
https://www.sciencedirect.com/topics/chemistry/electronegativity
Cho, Y.-S., N. Soyoung, S. Jeong, Y.-S. Kim, Low-cost fabrication of flexible water-repellent film by spray coating of a hydrophobic nanoparticle dispersion, Journal of Dispersion Science and Technology, 41, 10, 2019, http://dx.doi.org/10.1080/01932691.2019.1627883
https://www.scribd.com/document/212369617/Fluorinated-Pharmaceuticals
Shabir, G., A. Saeed, W. Zahid, F. Naseer, Z. Riaz, N. Khalil, N., Muneeba, F. Albericio, Chemistry and Pharmacology of Fluorinated Drugs Approved by the FDA (2016–2022), Pharmaceuticals, 16, 1162, 2023, https://doi.org/10.3390/ ph16081162
Patai’s Chemistry of Functional Groups Modern Fluorine-Containing Agrochemicals https://onlinelibrary.wiley.com/doi/abs/10.1002/9780470682531.pat1013#:~:text=Today%2C%20modern%20fluorine-containing%20agrochemicals%20are%20of%20the%20utmost,the%20food%20supply%20for%20a%20growing%20world%20population.?msockid=02ec270e3493696236cd33ab356f68a3
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7946751/pdf/nihms-1662362.pdf
https://banpfasmanifesto.org/en/, Checked August 18th, 2024
Tang, C., Y. Wang, H. Hong, Unraveling the link between heavy metals, perfluoroalkyl substances and depression: Insights from epidemiological and bioinformatics strategies. Ecotoxicology and Environmental Safety. https://doi.org/10.1016/j.ecoenv.2024.116482
Kim, J. I, B.-N. Kim, Y. A. Lee, C. H. Shin, Y.-C. Hong, L. D. Dossing, G. Hildebrandt, Y.-H. Lim, Association between early-childhood exposure to perfluoroalkyl substances and hyperactivity disorder (ADHD): A prospective cohort study. Science of the Total Environment, 879, 163081, 2023.
Harris, M. H. E. Oken, S. L. Rifas-Shiman, A. M. Calafat, D. C. Bellinger, T. F. Webster, R. F. White, S. K. Sagiv, Prenatal and childhood exposure to per- and polyfluoroalkyl substances (PFAS) and child executive function and behavioral problems. Environmental Research, 202, 111621, 2021, https://doi.org/10.1016/j.envres.2021.111621
Basaly, V., J. Hill, S. W. Bihaqi, E. Marques, A. L. Slitt, N. H. Zawia, Developmental Perfluorooctanesulfonic acid (PFOS) Exposure as a Potential Risk Factor for Late-Onset Alzheimer’s Disease in CD-1 Mice and SH-SY5Y Cells. DOI: 10.1016/j.neuro.2021.06.008
https://data.geus.dk/pure-pdf/GEUS-R_2024-4_web.pdf
https://link.springer.com/article/10.1007/s11356-024-32082-x
https://www.anourishingharvest.com/articles/pfas-and-plants
https://www.cieh.org/ehn/food-safety-integrity/2024/april/pan-uk-data-shows-toxic-pfas-in-uk-fruit-vegetables-and-spices/
https://www.foodandwaterwatch.org/2024/02/08/pfas-sewage-sludge/
https://regionsyddanmark.dk/media/2jhjpev5/clean_unders%C3%B8gelser-af-kystn%C3%A6r-pfas-forurening_syddanske-udviklingspulje-22-52316_rapport-03-10_2023_optimized.pdf
https://www.efsa.europa.eu/en/news/pfas-food-efsa-assesses-risks-and-sets-tolerable-intake
https://cot.food.gov.uk/sites/default/files/2022-10/TOX-2022-53 PFAS further work_Final.pdf
https://cot.food.gov.uk/sites/default/files/2022-10/PFAS final draft statement V2_September 2022_AB_OOS - SW Updated 17-10-22.pdf
https://foedevarestyrelsen.dk/kost-og-foedevarer/foedevaresikkerhed/kemiske-stoffer-og-toksiner/miljoeforureninger-i-foedevarer/pfas/pfas-i-foedevarer
Cappelli, F., Y. A., Bamai, K., Van Hoey, D., Kim, A. Covaci, Occurrence of short- and ultra-short chain PFAS in drinking water from Flanders (Belgium) and implications for human exposure. Environmental Research, 119753, 2024, https://doi.org/10.1016/j.envres.2024.119753
https://www.eea.europa.eu/en/european-zero-pollution-dashboards/indicators/pfas-in-eu-seas
https://mim.dk/nyheder/pressemeddelelser/2023/december/danmark-gaar-foran-i-arbejdet-med-at-begraense-pfas-i-vandmiljoe-og-spildevand
https://havhøst.dk/
https://phys.org/news/2024-04-ocean-propel-pfas.html
https://danskevv.dk/nyheder/pfas-i-havskum-en-kilde-til-forureninger-i-grundvandet/#:~:text=PFAS%20i%20havskum%3A%20En%20kilde%20til%20forureninger%20i,hvor%20fluorstofferne%20udg%C3%B8r%20en%20trussel%20for%20vores%20drikkevand.https://www.food.dtu.dk/newsarchive/2023/01/pfas-fundet-i-oekologiske-aeg
Zheng, G., S.M., Eick, A., Salamova, Elevated Levels of Ultrashort- and Short-Chain Perfluoroalkyl Acids in US Homes and People, Environmental Science & Technology. Environ. Sci. Technol., 57, pp. 15782−15793, 2023, https://pubs.acs.org/10.1021/acs.est.2c06715
Annual European Union greenhouse gas inventory 1990–2021 and inventory report 2023, April 15th, 2023. Submission to the UNFCCC Secretariat, https://www.eea.europa.eu/publications/annual-european-union-greenhouse-gas-2
https://unfccc.int/process-and-meetings/the-paris-agreement
https://www.unep.org/news-and-stories/press-release/nations-must-go-further-current-paris-pledges-or-face-global-warming
https://www.weforum.org/agenda/2023/09/prevent-1-5-degrees-celsius-climate-threshold/
https://www.bbc.com/news/science-environment-68110310
https://www.who.int/news/item/25-03-2014-7-million-premature-deaths-annually-linked-to-air-pollutionhttps://nyheder.tv2.dk/samfund/2022-08-05-her-er-de-15000-steder-der-mistaenkes-for-pfas-forurening