Uklanjanje organofosfatnog insekticida diazinona iz vodenih rastvora korišćenjem regenerisanog aktivnog uglja
Apstrakt
Voda je nezamenljiv resurs za život na Zemlji. Sve veći izazov savremenom društvu predstavlja i problem zagađenja vode koji, uz nedovoljno tretiranje otpadnih voda, ozbiljno ugrožava ekološku ravnotežu i ljudsko zdravlje.
Reference
[1] Foo, K. Y., Hameed, B. H. (2010). Detoxification of pesticide waste via activated carbon adsorption process. Journal of Hazardous Materials, 175(1-3), 1–11.
[2] Saleh, I. A., Zouari, N., & Al-Ghouti, M. A. (2020). Removal of pesticides from water and wastewater: Chemical, physical and biological treatment approaches. Environmental Technology & Innovation, 101026.
[3] Chang, C.-F., Lee, S.-C. (2012). Adsorption behavior of pesticide methomyl on activated carbon in a high gravity rotating packed bed reactor. Water Research, 46(9), 2869–2880.
[4] Li, S., Li, W., Chen, H., Liu, F., Jin, S., Yin, X., Liu, B. (2018). Effects of calcium ion and pH on the adsorption/regeneration process by activated carbon permeable reactive barriers. RSC Advances, 8(30), 16834–16841.
[5] Shah, I. K., Pre, P., & Alappat, B. J. (2014). Effect of thermal regeneration of spent activated carbon on volatile organic compound adsorption performances. Journal of the Taiwan Institute of Chemical Engineers, 45(4), 1733–1738.
[6] Stupar, S., Vuksanović, M., Totovski, L., Jančić-Heinemann, R., Mijin, D. (2021). Adsorption Of Anthraquinone Dye Ab111 From Aqueous Solution Using Synthesized Alumina-Iron Oxide Doped Particles, Science Of Sintering, 53(1):91-117
[7] Stupar, S. L., Grgur, B. N., Radišić, M. M., Onjia, A. E., Ivanković, N. D., Tomašević, A. V., Mijin, D. Ž. (2020). Oxidative degradation of Acid Blue 111 by electro-assisted Fenton process. Journal of Water Process Engineering, 36, 101394.
[8] Stojisavljević, P., Ivanković, N., Mijin, D., Tomašević, A., Grgur, B., Samolov, A., Stupar, S. (2022). Direct Electrochemical Degradation Of Carbamate Pesticide Methomyl Using Irox Anode, International Journal Of Electrochemical Science, Vol.17, Pp.220757.
[9] Stupar, S., Grgur, B., Onjia, A., Mijin, D. (2017). Direct And Indirect Electrochemical Degradation Of Acid Blue 111 Using Irox Anode, International Journal Of Electrochemical Science, Vol.12, Pp.8564-8577.
[10] Salvador, F., Martin-Sanchez, N., Sanchez-Hernandez, R., Sanchez-Montero, M. J., Izquierdo, C. (2015). Regeneration of carbonaceous adsorbents. Part II: Chemical, Microbiological and Vacuum Regeneration. Microporous and Mesoporous Materials, 202, 277–296.
[11] Pełech, R., Milchert, E., Wróblewska, A. (2005). Desorption of chloroorganic compounds from a bed of activated carbon. Journal of Colloid and Interface Science, 285(2), 518–524.
[12] Shah, I. K., Pre, P., Alappat, B. J. (2014). Effect of thermal regeneration of spent activated carbon on volatile organic compound adsorption performances. Journal of the Taiwan Institute of Chemical Engineers, 45(4), 1733–1738.
[14] Ying, X., Kim, G., Han, I., Sheng, J., Mei, Q., Kim, Y. (2022). High Efficiency Regeneration Performance Of Exhausted Activated Carbon By Superheated Steam And Comparison With Conventional Chemical Regeneration Method. KSCE Journal of Civil Engineering, 26(8)
[15] Dhaouadi, A., Monser, L., Adhoum, N. (2010). Removal of rotenone insecticide by adsorption onto chemically modified activated carbons. Journal of Hazardous Materials, 181(1-3), 692–699.
[16] Gupta, V. K., Ali, I., Suhas, & Saini, V. K. (2006). Adsorption of 2,4-D and carbofuran pesticides using fertilizer and steel industry wastes. Journal of Colloid and Interface Science, 299(2), 556–563.
[17] Wang, J., Guo, X. (2020). Adsorption kinetic models: Physical meanings, applications, and solving methods. Journal of Hazardous Materials, 390, 122156.
[18] Largitte, L., Pasquier, R. (2016). A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chemical Engineering Research and Design, 109, 495–504.
[19] Foo, K. Y., Hameed, B. H. (2010). Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156(1), 2–10.
[20] Rusmirović, J. D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V. B. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environmental Science and Pollution Research, 26(12), 12379–12398.
[21] Liu, C.-H., Chuang, Y.-H., Chen, T.-Y., Tian, Y., Li, H., Wang, M.-K., Zhang, W. (2015). Mechanism of Arsenic Adsorption on Magnetite Nanoparticles from Water: Thermodynamic and Spectroscopic Studies. Environmental Science & Technology, 49(13), 7726–7734.
[22] Bizerea Spiridon, O., Pitulice, L. (2014). Response to “Using of ‘pseudo-second-order model’ in adsorption”, comment letter on “Phenol removal from wastewater by adsorption on zeolitic composite” [Bizerea Spiridon et al., Environ Sci Pollut Res (2013) 20:6367–6381]. Environmental Science and Pollution Research, 21(11), 7236–7237.
[23] Liu, Y. (2008). New insights into pseudo-second-order kinetic equation for adsorption. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 320(1-3), 275–278.
[24] Chingombe, P., Saha, B., & Wakeman, R. J. (2006). Effect of surface modification of an engineered activated carbon on the sorption of 2,4-dichlorophenoxy acetic acid and benazolin from water. Journal of Colloid and Interface Science, 297(2), 434–442.
[25] Salman, J. M., Njoku, V. O., Hameed, B. H. (2011). Bentazon and carbofuran adsorption onto date seed activated carbon: Kinetics and equilibrium. Chemical Engineering Journal, 173(2), 361–368.
[26] Nethaji, S., Sivasamy, A., Mandal, A. B. (2012). Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass. International Journal of Environmental Science and Technology, 10(2), 231–242.
[27] Ren, L., Zhang, J., Li, Y., Zhang, C. (2011). Preparation and evaluation of cattail fiber-based activated carbon for 2,4-dichlorophenol and 2,4,6-trichlorophenol removal. Chemical Engineering Journal, 168(2), 553–561.
[28] Popovic, A. L., Rusmirovic, J. D., Velickovic, Z., Radovanovic, Z., Ristic, M., Pavlovic, V. P., Marinkovic, A. D. (2019). Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. International Journal of Biological Macromolecules.
[29] Veličković, Z., Vuković, G. D., Marinković, A. D., Moldovan, M.-S., Perić-Grujić, A. A., Uskoković, P. S., Ristić, M. Đ. (2012). Adsorption of arsenate on iron(III) oxide coated ethylenediamine functionalized multiwall carbon nanotubes. Chemical Engineering Journal, 181-182, 174–181.
[30] Vuković, G. D., Marinković, A. D., Škapin, S. D., Ristić, M. Đ., Aleksić, R., Perić-Grujić, A. A., Uskoković, P. S. (2011). Removal of lead from water by amino modified multi-walled carbon nanotubes. Chemical Engineering Journal, 173(3), 855–865.
[31] Budimirović, D., Veličković, Z. S., Djokić, V. R., Milosavljević, M., Markovski, J., Lević, S., & Marinković, A. D. (2017). Efficient As(V) removal by α -FeOOH and α -FeOOH/ α -MnO 2 embedded PEG-6-arm functionalized multiwall carbon nanotubes. Chemical Engineering Research and Design, 119, 75–86.
[32] Li, X., Wang, Z., Liang, H., Ning, J., Li, G., Zhou, Z. (2017). Chitosan modification persimmon tannin bioadsorbent for highly efficient removal of Pb(II) from aqueous environment: the adsorption equilibrium, kinetics and thermodynamics. Environmental Technology, 1–13.
[33] Derafa, G., Zaghouane-Boudiaf, H. (2018). Urtica dioica leaves-calcium alginate as a natural, low cost and very effective bioadsorbent beads in elimination of dyes from aqueous medium: Equilibrium isotherms and thermodynamic studies. International Journal of Biological Macromolecules. 124, 915-921.
[34] Karanac, M., Đolić, M., Veličković, Z., Kapidžić, A., Ivanovski, V., Mitrić, M., Marinković, A. (2018). Efficient multistep arsenate removal onto magnetite modified fly ash. Journal of Environmental Management, 224, 263–276.
[2] Saleh, I. A., Zouari, N., & Al-Ghouti, M. A. (2020). Removal of pesticides from water and wastewater: Chemical, physical and biological treatment approaches. Environmental Technology & Innovation, 101026.
[3] Chang, C.-F., Lee, S.-C. (2012). Adsorption behavior of pesticide methomyl on activated carbon in a high gravity rotating packed bed reactor. Water Research, 46(9), 2869–2880.
[4] Li, S., Li, W., Chen, H., Liu, F., Jin, S., Yin, X., Liu, B. (2018). Effects of calcium ion and pH on the adsorption/regeneration process by activated carbon permeable reactive barriers. RSC Advances, 8(30), 16834–16841.
[5] Shah, I. K., Pre, P., & Alappat, B. J. (2014). Effect of thermal regeneration of spent activated carbon on volatile organic compound adsorption performances. Journal of the Taiwan Institute of Chemical Engineers, 45(4), 1733–1738.
[6] Stupar, S., Vuksanović, M., Totovski, L., Jančić-Heinemann, R., Mijin, D. (2021). Adsorption Of Anthraquinone Dye Ab111 From Aqueous Solution Using Synthesized Alumina-Iron Oxide Doped Particles, Science Of Sintering, 53(1):91-117
[7] Stupar, S. L., Grgur, B. N., Radišić, M. M., Onjia, A. E., Ivanković, N. D., Tomašević, A. V., Mijin, D. Ž. (2020). Oxidative degradation of Acid Blue 111 by electro-assisted Fenton process. Journal of Water Process Engineering, 36, 101394.
[8] Stojisavljević, P., Ivanković, N., Mijin, D., Tomašević, A., Grgur, B., Samolov, A., Stupar, S. (2022). Direct Electrochemical Degradation Of Carbamate Pesticide Methomyl Using Irox Anode, International Journal Of Electrochemical Science, Vol.17, Pp.220757.
[9] Stupar, S., Grgur, B., Onjia, A., Mijin, D. (2017). Direct And Indirect Electrochemical Degradation Of Acid Blue 111 Using Irox Anode, International Journal Of Electrochemical Science, Vol.12, Pp.8564-8577.
[10] Salvador, F., Martin-Sanchez, N., Sanchez-Hernandez, R., Sanchez-Montero, M. J., Izquierdo, C. (2015). Regeneration of carbonaceous adsorbents. Part II: Chemical, Microbiological and Vacuum Regeneration. Microporous and Mesoporous Materials, 202, 277–296.
[11] Pełech, R., Milchert, E., Wróblewska, A. (2005). Desorption of chloroorganic compounds from a bed of activated carbon. Journal of Colloid and Interface Science, 285(2), 518–524.
[12] Shah, I. K., Pre, P., Alappat, B. J. (2014). Effect of thermal regeneration of spent activated carbon on volatile organic compound adsorption performances. Journal of the Taiwan Institute of Chemical Engineers, 45(4), 1733–1738.
[14] Ying, X., Kim, G., Han, I., Sheng, J., Mei, Q., Kim, Y. (2022). High Efficiency Regeneration Performance Of Exhausted Activated Carbon By Superheated Steam And Comparison With Conventional Chemical Regeneration Method. KSCE Journal of Civil Engineering, 26(8)
[15] Dhaouadi, A., Monser, L., Adhoum, N. (2010). Removal of rotenone insecticide by adsorption onto chemically modified activated carbons. Journal of Hazardous Materials, 181(1-3), 692–699.
[16] Gupta, V. K., Ali, I., Suhas, & Saini, V. K. (2006). Adsorption of 2,4-D and carbofuran pesticides using fertilizer and steel industry wastes. Journal of Colloid and Interface Science, 299(2), 556–563.
[17] Wang, J., Guo, X. (2020). Adsorption kinetic models: Physical meanings, applications, and solving methods. Journal of Hazardous Materials, 390, 122156.
[18] Largitte, L., Pasquier, R. (2016). A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chemical Engineering Research and Design, 109, 495–504.
[19] Foo, K. Y., Hameed, B. H. (2010). Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156(1), 2–10.
[20] Rusmirović, J. D., Obradović, N., Perendija, J., Umićević, A., Kapidžić, A., Vlahović, B., Pavlović, V. B. (2019). Controllable synthesis of Fe3O4-wollastonite adsorbents for efficient heavy metal ions/oxyanions removal. Environmental Science and Pollution Research, 26(12), 12379–12398.
[21] Liu, C.-H., Chuang, Y.-H., Chen, T.-Y., Tian, Y., Li, H., Wang, M.-K., Zhang, W. (2015). Mechanism of Arsenic Adsorption on Magnetite Nanoparticles from Water: Thermodynamic and Spectroscopic Studies. Environmental Science & Technology, 49(13), 7726–7734.
[22] Bizerea Spiridon, O., Pitulice, L. (2014). Response to “Using of ‘pseudo-second-order model’ in adsorption”, comment letter on “Phenol removal from wastewater by adsorption on zeolitic composite” [Bizerea Spiridon et al., Environ Sci Pollut Res (2013) 20:6367–6381]. Environmental Science and Pollution Research, 21(11), 7236–7237.
[23] Liu, Y. (2008). New insights into pseudo-second-order kinetic equation for adsorption. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 320(1-3), 275–278.
[24] Chingombe, P., Saha, B., & Wakeman, R. J. (2006). Effect of surface modification of an engineered activated carbon on the sorption of 2,4-dichlorophenoxy acetic acid and benazolin from water. Journal of Colloid and Interface Science, 297(2), 434–442.
[25] Salman, J. M., Njoku, V. O., Hameed, B. H. (2011). Bentazon and carbofuran adsorption onto date seed activated carbon: Kinetics and equilibrium. Chemical Engineering Journal, 173(2), 361–368.
[26] Nethaji, S., Sivasamy, A., Mandal, A. B. (2012). Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass. International Journal of Environmental Science and Technology, 10(2), 231–242.
[27] Ren, L., Zhang, J., Li, Y., Zhang, C. (2011). Preparation and evaluation of cattail fiber-based activated carbon for 2,4-dichlorophenol and 2,4,6-trichlorophenol removal. Chemical Engineering Journal, 168(2), 553–561.
[28] Popovic, A. L., Rusmirovic, J. D., Velickovic, Z., Radovanovic, Z., Ristic, M., Pavlovic, V. P., Marinkovic, A. D. (2019). Novel amino-functionalized lignin microspheres: High performance biosorbent with enhanced capacity for heavy metal ion removal. International Journal of Biological Macromolecules.
[29] Veličković, Z., Vuković, G. D., Marinković, A. D., Moldovan, M.-S., Perić-Grujić, A. A., Uskoković, P. S., Ristić, M. Đ. (2012). Adsorption of arsenate on iron(III) oxide coated ethylenediamine functionalized multiwall carbon nanotubes. Chemical Engineering Journal, 181-182, 174–181.
[30] Vuković, G. D., Marinković, A. D., Škapin, S. D., Ristić, M. Đ., Aleksić, R., Perić-Grujić, A. A., Uskoković, P. S. (2011). Removal of lead from water by amino modified multi-walled carbon nanotubes. Chemical Engineering Journal, 173(3), 855–865.
[31] Budimirović, D., Veličković, Z. S., Djokić, V. R., Milosavljević, M., Markovski, J., Lević, S., & Marinković, A. D. (2017). Efficient As(V) removal by α -FeOOH and α -FeOOH/ α -MnO 2 embedded PEG-6-arm functionalized multiwall carbon nanotubes. Chemical Engineering Research and Design, 119, 75–86.
[32] Li, X., Wang, Z., Liang, H., Ning, J., Li, G., Zhou, Z. (2017). Chitosan modification persimmon tannin bioadsorbent for highly efficient removal of Pb(II) from aqueous environment: the adsorption equilibrium, kinetics and thermodynamics. Environmental Technology, 1–13.
[33] Derafa, G., Zaghouane-Boudiaf, H. (2018). Urtica dioica leaves-calcium alginate as a natural, low cost and very effective bioadsorbent beads in elimination of dyes from aqueous medium: Equilibrium isotherms and thermodynamic studies. International Journal of Biological Macromolecules. 124, 915-921.
[34] Karanac, M., Đolić, M., Veličković, Z., Kapidžić, A., Ivanovski, V., Mitrić, M., Marinković, A. (2018). Efficient multistep arsenate removal onto magnetite modified fly ash. Journal of Environmental Management, 224, 263–276.
Objavljeno
2026-07-21
Kako citirati
GUJANIČIĆ, Vanja et al.
Uklanjanje organofosfatnog insekticida diazinona iz vodenih rastvora korišćenjem regenerisanog aktivnog uglja.
Procesna tehnika, [S.l.], v. 36, n. 1, p. 26-32, july 2026.
ISSN 2217-2319.
Dostupno na: <https://izdanja.smeits.rs/index.php/procteh/article/view/8368>. Datum pristupa: 17 oct. 2026
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Procesne tehnologije
