Modeliranje procesa pirolize biomase
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May 10, 2017
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Apstrakt
Na osnovu prikuplјenih literaturnih podataka pirolize različitih vrsta polјoprivrednih bilјnih ostataka, razvijen je statički model procesa pirolize. Na osnovu analize literaturnih podataka, definisane su empirijske jednačine za određivanje količine i sastava produkata pirolize (ter, gas, koksni ostatak) u zavisnosti od temperature procesa. Validacija modela je sprovedena poređenjem eksperimentalnih i literaturnih podataka sa rezultatima modela. Model pokazuje zadovolјavajuću tačnost i može se koristiti za analizu procesa pirolize različitih vrsta biomase (količina i sastav produkata pirolize, definisanje uticajnih parametra procesa itd.).
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Kako citirati
TRNINIĆ, Marta et al.
Modeliranje procesa pirolize biomase.
Zbornik Međunarodnog kongresa o procesnoj industriji – Procesing, [S.l.], v. 28, n. 1, p. 277-292, may 2017.
Dostupno na: <https://izdanja.smeits.rs/index.php/ptk/article/view/2549>. Datum pristupa: 16 mar. 2026
Sekcija
Tehnička regulativa, standardizacija i sistem kvaliteta
Reference
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15. Toshiyuki Iwasaki, Seiichi Suzuki, and T. Kojima, Influence of Biomass Pyrolysis Temperature, Heating Rate and Type of Biomass on Produced Char in a Fluidized Bed Reactor. Energy and Environment Research, 2014. 4(2).
16. Zanzi, R., K. Sjöström, and E. Björnbom, Rapid pyrolysis of agricultural residues at high temperature. Biomass and Bioenergy, 2002. 23(5): p. 357-366.
17. Ioannidou, O., et al., Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations. Renewable and Sustainable Energy Reviews, 2009. 13(4): p. 750-762.
18. Cao, Q., et al., Pyrolytic behavior of waste corn cob. Bioresource Technology, 2004. 94(1): p. 83-89.
19. Demirbas, A., Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues. Journal of Analytical and Applied Pyrolysis, 2004. 72(2): p. 243-248.
20. Brownsort, P.A., UKBRC - Biomass Pyrolysis Process: Review of Scope, Control and Variability. 2009, UK Biochar Research Center.
21. BROWNSORT, P.A., BIOMASS PYROLYSIS PROCESSES: PERFORMANCE PARAMETERS AND THEIR INFLUENCE ON BIOCHAR SYSTEM BENEFITS. 2009, University of Edinburgh,.
22. Neves, D., et al., Characterization and prediction of biomass pyrolysis products. Progress Energy Combustion Sci-ence, 2011. 37: p. 611 - 630.
23. Antal, M.J., et al., Attainment of the Theoretical Yield of Carbon from Biomass. Industrial & Engineering Chemistry Research, 2000. 39(11): p. 4024-4031.
24. Antal, M.J., et al., High-Yield Biomass Charcoal – . Energy & Fuels, 1996. 10(3): p. 652-658.
25. Antal, M.J. and M. Grønli, The Art, Science, and Technology of Charcoal Production – . Industrial & Engineering Chemistry Research, 2003. 42(8): p. 1619-1640.
26. Mullen, C.A., et al., Analysis and Comparison of Bio-Oil Produced by Fast Pyrolysis from Three Barley Biomass/Byproduct Streams. Energy & Fuels, 2009. 24(1): p. 699-706.
27. Agblevor, F. 2011: WO International Patent Application 2011/103313 A2.
28. Agblevor, F.A., S. Besler, and A.E. Wiselogel, Fast Pyrolysis of Stored Biomass Feedstocks. Energy & Fuels, 1995. 9(4): p. 635-640.
29. Beis, S.H., Ö. Onay, and Ö.M. Koçkar, Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions. Renewable Energy, 2002. 26(1): p. 21-32.
30. Schröder, E., Experiments on the pyrolysis of large beechwood particles in fixed beds. Journal of Analytical and Applied Pyrolysis, 2004. 71(2): p. 669-694.
31. Nunn, T.R., et al., Product compositions and kinetics in the rapid pyrolysis of milled wood lignin. Industrial & Engineering Chemistry Process Design and Development, 1985. 24(3): p. 844-852.
32. Choi, J.W. Features of fast pyrolysis of woody biomass and evaluation of biooil upgrading process with noble metal catalysts. in 2nd FOREBIOM Workshop - Potentials of Biochar to Mitigate Climate Change. 2014. Busian, Korea.
33. Ateş, F., E. Pütün, and A.E. Pütün, Fast pyrolysis of sesame stalk: yields and structural analysis of bio-oil. Journal of Analytical and Applied Pyrolysis, 2004. 71(2): p. 779-790.
34. Karamarkovic, R. and V. Karamarkovic, Energy and exergy analysis of biomass gasification at different temperatures. Energy, 2010. 35(2): p. 537-549.
2. Bridgwater, A.V. and M.L. Cottam, Opportunities for biomass pyrolysis liquids production and upgrading. Energy & Fuels, 1992. 6(2): p. 113-120.
3. Brownsort, P., Biomass Pyrolysis Processes: Review of Scope, Control and Variability. UKBRC Working Paper 5, 2009.
4. Bridgwater, A.V., Principles and practice of biomass fast pyrolysis processes for liquids. Journal of Analytical and Applied Physics, 1999. 51 ((1 – 2)): p. 3 – 22.
5. Zabaniotou, A.A., et al., Olive residues (cuttings and kernels) rapid pyrolysis product yields and kinetics. Biomass and Bioenergy, 2000. 18(5): p. 411-420.
6. Punsuwan, N. and C. Tangsathitkulchai, Product Characterization and Kinetics of Biomass Pyrolysis in a Three-Zone Free-Fall Reactor. International Journal of Chemical Engineering and Applications, 2014: p. 10.
7. Wang, L., et al., Is Elevated Pressure Required To Achieve a High Fixed-Carbon Yield of Charcoal from Biomass? Part 1: Round-Robin Results for Three Different Corncob Materials. Energy & Fuels, 2011. 25(7): p. 3251-3265.
8. Encinar, J.M., et al., Pyrolysis of maize, sunflower, grape and tobacco residues. Journal of Chemical Technology & Biotechnology, 1997. 70(4): p. 400-410.
9. Mullen, C.A., et al., Bio-oil and bio-char production from corn cobs and stover by fast pyrolysis. Biomass and Bioenergy, 2010. 34(1): p. 67-74.
10. Raveendran, K., A. Ganesh, and K.C. Khilar, Influence of mineral matter on biomass pyrolysis characteristics. Fuel, 1995. 74(12): p. 1812-1822.
11. Scott, D.S., J. Piskorz, and D. Radlein, Liquid products from the continuous flash pyrolysis of biomass. Industrial & Engineering Chemistry Process Design and Development, 1985. 24(3): p. 581-588.
12. Fagbemi, L., L. Khezami, and R. Capart, Pyrolysis products from different biomasses: application to the thermal cracking of tar. Applied Energy, 2001. 69(4): p. 293-306.
13. Di Blasi, C., et al., Product Distribution from Pyrolysis of Wood and Agricultural Residues. Industrial & Engineering Chemistry Research, 1999. 38(6): p. 2216-2224.
14. Onay, O. and O. Kockar, Technical note: slow, fast and flash pyrolysis of rape seed. Renew Energy, 2003. 28: p. 2417 - 2433.
15. Toshiyuki Iwasaki, Seiichi Suzuki, and T. Kojima, Influence of Biomass Pyrolysis Temperature, Heating Rate and Type of Biomass on Produced Char in a Fluidized Bed Reactor. Energy and Environment Research, 2014. 4(2).
16. Zanzi, R., K. Sjöström, and E. Björnbom, Rapid pyrolysis of agricultural residues at high temperature. Biomass and Bioenergy, 2002. 23(5): p. 357-366.
17. Ioannidou, O., et al., Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations. Renewable and Sustainable Energy Reviews, 2009. 13(4): p. 750-762.
18. Cao, Q., et al., Pyrolytic behavior of waste corn cob. Bioresource Technology, 2004. 94(1): p. 83-89.
19. Demirbas, A., Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues. Journal of Analytical and Applied Pyrolysis, 2004. 72(2): p. 243-248.
20. Brownsort, P.A., UKBRC - Biomass Pyrolysis Process: Review of Scope, Control and Variability. 2009, UK Biochar Research Center.
21. BROWNSORT, P.A., BIOMASS PYROLYSIS PROCESSES: PERFORMANCE PARAMETERS AND THEIR INFLUENCE ON BIOCHAR SYSTEM BENEFITS. 2009, University of Edinburgh,.
22. Neves, D., et al., Characterization and prediction of biomass pyrolysis products. Progress Energy Combustion Sci-ence, 2011. 37: p. 611 - 630.
23. Antal, M.J., et al., Attainment of the Theoretical Yield of Carbon from Biomass. Industrial & Engineering Chemistry Research, 2000. 39(11): p. 4024-4031.
24. Antal, M.J., et al., High-Yield Biomass Charcoal – . Energy & Fuels, 1996. 10(3): p. 652-658.
25. Antal, M.J. and M. Grønli, The Art, Science, and Technology of Charcoal Production – . Industrial & Engineering Chemistry Research, 2003. 42(8): p. 1619-1640.
26. Mullen, C.A., et al., Analysis and Comparison of Bio-Oil Produced by Fast Pyrolysis from Three Barley Biomass/Byproduct Streams. Energy & Fuels, 2009. 24(1): p. 699-706.
27. Agblevor, F. 2011: WO International Patent Application 2011/103313 A2.
28. Agblevor, F.A., S. Besler, and A.E. Wiselogel, Fast Pyrolysis of Stored Biomass Feedstocks. Energy & Fuels, 1995. 9(4): p. 635-640.
29. Beis, S.H., Ö. Onay, and Ö.M. Koçkar, Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions. Renewable Energy, 2002. 26(1): p. 21-32.
30. Schröder, E., Experiments on the pyrolysis of large beechwood particles in fixed beds. Journal of Analytical and Applied Pyrolysis, 2004. 71(2): p. 669-694.
31. Nunn, T.R., et al., Product compositions and kinetics in the rapid pyrolysis of milled wood lignin. Industrial & Engineering Chemistry Process Design and Development, 1985. 24(3): p. 844-852.
32. Choi, J.W. Features of fast pyrolysis of woody biomass and evaluation of biooil upgrading process with noble metal catalysts. in 2nd FOREBIOM Workshop - Potentials of Biochar to Mitigate Climate Change. 2014. Busian, Korea.
33. Ateş, F., E. Pütün, and A.E. Pütün, Fast pyrolysis of sesame stalk: yields and structural analysis of bio-oil. Journal of Analytical and Applied Pyrolysis, 2004. 71(2): p. 779-790.
34. Karamarkovic, R. and V. Karamarkovic, Energy and exergy analysis of biomass gasification at different temperatures. Energy, 2010. 35(2): p. 537-549.