Termijske analize fizičko-hemijskih promena u aktivnom uglju tokom njegove regeneracije
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Apstrakt
U procesu visokotemperaturske regeneracije zasićenog aktivnog uglja odvijaju se složene fizičko-hemijske transformacije materije čiji tok zavisi od velikog broja uticajnih parametra. Zbog te činjenice jedino se na osnovu eksperimentalnih istraživanja procesa visokotemperaturske regeneracije mogu donositi ispravni zaključci o mehanizama, kinetici i dinamici procesa koji se odvijaju. U radu su predstavljeni rezultati termijskih analiza procesa visokotemperaturske regeneracije zasićenog aktivnog uglja dobijenog od ljuske kokosovog oraha koji se koristi za prečišćavanje vode za piće. Na osnovu rezultata termogravimetrijske analize (TG kriva), derivirane termogravimetrijske analize (DTG kriva) i difrencijalne termijske analize (DTA) postavljeno je niz hipoteza o pojedinim fazama procesa regeneracije aktivnog uglja, procesnim parametrima pri kojima se određene faze procesa regeneracije odvijaju i katalitičkom uticaju neorganskih materijala na proces regeneracije. Zagrevanje uzoraka u derivatografu je rađeno u oksidacionoj i redukcionoj atmosferi, a uzorci aktivnog uglja koji su ispitivani su bili uzorci novog, zasićenog i prethodno regenerisanog aktivnog uglja. Poređenje uočenih pojava pri zagrevanju uzoraka aktivnog uglja do 1000oC u oksidacionoj i redukcionoj atmosferi i dijagrama termijskih analiza su bili osnova za ocenu ponašanja aktivnih ugljeva pri termičkom tretmanu.
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Reference
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