Uticaj strukture azo boja na fotonaponske karakteristike solarnih ćelija aktiviranih bojom

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Luka Matović Juliana Tadić Aleksandra Mašulović Nemanja Trišović Jelena Lađarević Dušan Mijin

Apstrakt

 


Solarne ćelije sa fotoosetljivom bojom (DSSC), kao nova solarna tehnologija i glavni konkurent solarnih ćelija baziranih na silicijumu, u jeku su istraživanja poslednje dve decenije. U ovom radu sintetisano je šest azo boja na bazi benzoeve i cimetne kiseline, koje imaju ulogu generatora nosioca naelektrisanja u DSSC sistemu. Jedinjenja su okarakterisana temperaturama topljenja, UV-Vis, FT-IR, 1H i 13C NMR spektroskopijom. Snimljene su strujno-naponske karakteristike solarnih ćelija i određeni su osnovni operativni parametri: gustina struje kratkog spoja (JSC) i napon otvorenog kola (VOC). Na osnovu dobijenih rezultata utvrđeno je da 4-(2-hidroksinaftalen-1-ilazo)cimetna kiselina, kao i 4-[4’-(N,N-dimetilamino)fenilazo]cimetna kiselina daju najveću efikasnost fotokonverzije.


 


 


 

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Kako citirati
MATOVIĆ, Luka et al. Uticaj strukture azo boja na fotonaponske karakteristike solarnih ćelija aktiviranih bojom. Zbornik Međunarodnog kongresa o procesnoj industriji – Procesing, [S.l.], v. 32, n. 1, p. 219-224, july 2019. Dostupno na: <https://izdanja.smeits.rs/index.php/ptk/article/view/4958>. Datum pristupa: 23 oct. 2019
Sekcija
Inženjerstvo životne sredine i održivi razvoj

Reference

[1] Nakajima K., K. Ohta, H. Katayanagi, K. Mitsuke, Photoexcitation and electron injection processes in azo dyes adsorbed on nanocrystalline TiO2 films, Chemical Physics Letters, 510 (2011), 4-6, pp. 228-233.
[2] Han M., X. Zhang, X. Zhang, C. Liao, B. Zhu, Azo-coupled zinc phthalocyanines: Towards broad absorption and application in dye-sensitized solar cells, Polyhedron, 85 (2015), pp. 864-873.
[3] Dinçalp H., F. Toker, I. Durucasu, N. Avcibaşi, S. Icli, New thiopene-based azo ligands containing azo methane group in the main chain for determination of copper(II) ions, Dyes and Pigments, 75 (2007), 1, pp. 11-24.
[4] Grätzel M., Dye-sensitized solar cells, Journal of Photochemistry and Photobiology C: Pho-tochemistry Reviews, 4 (2003), 2, pp. 145-153.
[5] Novir S.B., S. M. Hashemianzadeh, Quantum chemical investigation of structural and electro-nic properties of trans- and cis-structures of some azo dyes for dye-sensitized solar cells, Computational and Theoretical Chemistry, 1102 (2017), pp. 87-97.
[6] Prajongtat P., S. Suramitr, S. Nokbin, K. Nakajima, K. Mitsuke, Density functional theory study of adsorption geometries and electronic structurs of azo-dye based molecules on anatase TiO2 surface for dye-sensitized solar cell applications, Journal of Molecular graphics and Mo-deling, 76 (2017), pp. 551-561.
[7] Faridoon, A. L. Edkins, M. Isaacs, D. Mnkandhla, H. C. Hoppe, Synthesis and evaluation of substituted 4-(N-benzylamino)cinnamate esters as potential anti-cancer agents and HIV-1 integrase inhibitors, Bioorganic & Medicinal Chemistry Letters, 26 (2016), 15, pp. 3810-3812.
[8] Skinner W.A., M. G. M. Schelstraete, B. R. Baker, Potential Anticancer agents. XLVIII. Analogs of Chlorambucil. VI.2 Ring Isomers, Journal of Organic Chemistry, 26 (1961), pp. 1554-1557.
[9] Fukuda H., K. Nishikawa, Y. Fukunaga, K. Okuda, K. Kodama, Synthesis of fluorescent molecular probes based on cis-cinnamic acid and molecular imaging of lettuce roots, Tetra-hedron, 72 (2016), 41, pp. 6492-6498.
[10] Haba O., H. Itabashi, S. Sato, K. Machida, T. Koda, UV-Induced Stable Planar Alignment of Nematic Liquid Crystals Using a Polypropyleneimine Dendrimer Having a Mesogen
224 • 32nd INTERNATIONAL CONGRESS ON PROCESS INDUSTRY
Consisting of Cinnamate and Azobenzene Moieties, Molecular Crystals and Liquid Crystals, 610 (2015), 1, pp. 201-209.
[11] Folcia C.L., I. Alonso, J. Ortega, J. Etxebarria, I. Pintre, Achiral Bent-Core Liquid Crystals with Azo and Azoxy Linkages: Structural and Nonlinear Optical Properties and Photoisomeri-zation, Chemistry of Materials, 18 (2016), 19, pp. 4617-4626.
[12] Adegoke O.A., O. S. Idowu, A. A. Olaniyi, Synthesis and spectroscopic characterization of 4-carboxyl-2,6-dinitrophenylazohydroxynaphthalenes, Dyes and Pigments, 77 (2008), 1, pp. 111-117.
[13] Zhang L., J. M. Cole, C. Dai, Variation in Optoelectronic Properties of azo Dye-Sensitized TiO2 Semicoductor Interfaces with Different Adsorption Anchors: Carboxylate, Sulfonate, Hidroxyl and Pyridyl Groups, ACS Applied Materials & Interfaces, 6 (2014), 10, pp. 7535-7546.
[14] Zhang L., J. M. Cole, TiO2-Assisted Photoisomerization of Azo Dyes Using Self-Assembled Monolayers: Case Study on para-Methyl red Towards Solar-Cell Applications, ACS Applied Materials & Interfaces, 6 (2014), 5, pp. 3742-3749.
[15] Chen X. C., T. Tao, Y. G. Wang , Y. X. Peng , W. Huang, Azo-hydrazone tautomerism observed from UV-Vis spectra by pH control and metal-ion complexation for two heterocyclic disperse yellow dyes, Dalton Transactions, 41 (2012), pp. 11107-11115.
[16] Mirković J., J. Rogan, D. Poleti, V. Vitnik, Ž. Vitnik, On the structures of 5-(4-, 3- and 2-methoxyphenylazo)-3-cyano-1-ethyl-6-hydroxy-4-methyl-2-pyrido