Prirodni adsorbenti na bazi metalnih oksida za uklanjanje jona olova i arsena iz vodenih rastvora

##plugins.themes.bootstrap3.article.main##

Tijana Stanišić Nataša Karić Milica Karanac Maja Đolić Mirjana Ristić Aleksandra Perić-Grujić

Apstrakt

Cilj ovog rada je bio ispitivanje efikasnosti sirovih mineralnih materijala koji imaju dobra adsorpciona i tehno-ekonomska svojstva primenljiva u realnim sistemima za uklanjanje jona teških metala, pre svega olova i arsena. Adsorpciona ispitivanja su izvršena u šaržnom sistemu. Kako bi se utvrdili optimalni uslovi, ispitana je efikasnost uklanjanja odabranih jona variranjem mase adsorbenta (5, 7,5, 10 i 20 mg). Materijali korišćeni u eksperimentalnom radu su mineralnog porekla, čiji sastav pretežno čine SiO2, Al2O3 i Fe2O3. Izvršena je njihova karakterizacija primenom rendgenske difrakcione analize (engl. X-Ray Difraction, XRD), infracrvene spektrometrije sa Furijeovom transformacijom (engl. Fourier-Transform Infrared Spectroscopy, FTIR) i skenirajuće elektronske mikroskopije (engl. scanning electron microscopy SEM). Maksimalna efikasnost uklanjanja jona olova iznosi 94,8 % na materijalu dominantnog sastava ilovače , dok je za jone arsena efikasnost 47,5 % na materijalu koji se bazira na peskovitoj ilovači.

##plugins.themes.bootstrap3.article.details##

Kako citirati
STANIŠIĆ, Tijana et al. Prirodni adsorbenti na bazi metalnih oksida za uklanjanje jona olova i arsena iz vodenih rastvora. Zbornik Međunarodnog kongresa o procesnoj industriji – Procesing, [S.l.], v. 34, n. 1, p. 43-48, july 2021. Dostupno na: <https://izdanja.smeits.rs/index.php/ptk/article/view/6565>. Datum pristupa: 23 oct. 2021 doi: https://doi.org/10.24094/ptk.021.34.1.43.
Sekcija
Procesi i postrojenja u pripremi i prečišćavanju vode u procesnoj industriji

Reference

Mihajlović, S., M. Vukčević, B. Pejić, A. Perić-Grujić, and M. Ristić, “Application of waste cotton yarn as adsorbent of heavy metal ions from single and mixed solutions,” Environ. Sci. Pollut. Res., vol. 27, no. 28, pp. 35769–35781, 2020.
[2] Pantić, K., Z. J. Bajić, Z. S. Veličković, V. R. Đokić, J. D. Rusmirović, A. D. Marinković, A. Perić-Grujić, “Adsorption performances of branched aminated waste polyacrylonitrile fibers: Experimental versus modelling study,” Desalin. Water Treat., vol. 171, pp. 223–249, 2019.
[3] Akpomie, K. G., F. A. Dawodu, and K. O. Adebowale, “Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential,” Alexandria Eng. J., vol. 54, no. 3, pp. 757–767, 2015.
[4] Veličković, Z., D. Antanasijević, A. Marinković, G. Vuković, A. Perić-Grujić, P. Uskoković, M. Ristić, “Adsorption of arsenate on iron(III) oxide coated ethylenediamine functionalized multiwall carbon nanotubes,” Chem. Eng. J., vol. 181–182, pp. 174–181, 2012.
[5] Wołowiec, M., M. Komorowska-kaufman, A. Pruss, G. Rzepa, and T. Bajda, “Removal of Heavy Metals and Metalloids from Water Using Drinking Water Treatment Residuals as Adsorbents : A Review,” Minerals, vol. 9, no. 8, pp. 1–17, 2019.
[6] Wagle, D. and H. J. Shipley, “Adsorption of Arsenic (V) to Titanium Dioxide Nanoparticles: Effect of Particle Size, Solid Concentration, and Other Metals,” Environ. Eng. Sci., vol. 33, no. 5, pp. 299–305, 2016.
[7] Đolić, M., V. N. Rajaković, M. N. Mitrić, A. E. Onjia, and L. J. Janković, “The effect of different extractants on lead desorption from a natural mineral,” vol. 324, pp. 221–231, 2015.
[8] Ogbu, I., K. Akpomie, A. Osunkunle, and S. Eze, “Sawdust-kaolinite composite as efficient sorbent for heavy metal ions,” Bangladesh J. Sci. Ind. Res., vol. 54, no. 1, pp. 99–110, 2019.
[9] Mahdavi, S., M. Jalali, and A. Afkhami, “Removal of heavy metals from aqueous solutions using Fe3O4, ZnO, and CuO nanoparticles,” J. Nanoparticle Res., vol. 14, no. 8, pp. 0–18, 2012.
[10] Awwad, A. M., M. W. Amer, and M. M. Al-aqarbeh, “TiO2-kaolinite nanocomposite prepared from the Jordanian Kaolin clay : Adsorption and thermodynamics of Pb (II) and Cd (II) ions in aqueous solution,” Chem. Int., vol. 6, no. 4, pp. 168–178, 2020.
[11] Agrafioti, E., D. Kalderis, and E. Diamadopoulos, “Arsenic and chromium removal from water using biochars derived from rice husk, organic solid wastes and sewage sludge,” J. Environ. Manage., vol. 133, pp. 309–314, 2014.
[12] Krauklis,A. E., R. Ozola-davidane, and J. Burlakovs, “FeOOH and Mn8O10Cl3 Modified Zeolites for As(V) Removal in Aqueous Medium,” no. March, 2017.
[13] Dewi, R., H. Agusnar, Z. Alfian, and Tamrin, “Characterization of technical kaolin using XRF, SEM, XRD, FTIR and its potentials as industrial raw materials,” J. Phys. Conf. Ser., vol. 1116, no. 4, pp. 0–6, 2018.
[14] Simić, V. and P. Uhlík, “Crystallite size distribution of clay minerals from selected Serbian clay deposits,” Geol. Anal. Balk. poluostrva, no. 67, pp. 109–116, 2006.
[15] Schoonover, J. E. and J. F. Crim, “An Introduction to Soil Concepts and the Role of Soils in Watershed Management,” J. Contemp. Water Res. Educ., vol. 154, no. 1, pp. 21–47, 2015.
[16] Margenot, A. J., F. J. Calderón, K. W. Goyne, F. N. Dmukome, and S. J. Parikh, “IR spectroscopy, soil analysis applications,” Encycl. Spectrosc. Spectrom., pp. 448–454, 2016.
[17] Karanac. M., M. Đolić, Z. Veličković, Ž. Kamberović, V. Pavićević, and A. Marinković, “Primena elektrofilterskog pepela modifikovanog sa getitom za uklanjanje As(v) iz vodenih rastvora,” Procesna Teh., vol. 31, no. 1, p. 28, 2019.
[18] Bernier, M. H., G. J. Levy, P. Fine, and M. Borisover, “Organic matter composition in soils irrigated with treated wastewater: FT-IR spectroscopic analysis of bulk soil samples,” Geoderma, vol. 209–210, pp. 233–240, 2013.
[19] Karanac, M., M. Đolić, Z. Veličković, A. Kapidžić, V. Ivanovski, M. Mitrić, A. Marinković, “Efficient multistep arsenate removal onto magnetite modified fly ash,” J. Environ. Manage., vol. 224, no. July, pp. 263–276, 2018.
[20] Ivanić, M., N. Vdović, S. de B. Barreto, V. Bermanec, and I. Sondi, “Mineralogy, surface properties and electrokinetic behaviour of kaolin clays derived from naturally occurring pegmatite and granite deposits,” Geol. Croat., vol. 68, no. 2, pp. 139–145, 2015.
[21] Sharifipour, F., S. Hojati, A. Landi, and A. Faz Cano, “Kinetics and Thermodynamics of Lead Adsorption from Aqueous Solutions Onto Iranian Sepiolite and Zeolite,” Int. J. Environ. Res., vol. 9, no. 3, pp. 1001–1010, 2015.
[22] Ishiguro M. and L. K. Koopal, “Surfactant adsorption to soil components and soils,” Adv. Colloid Interface Sci., vol. 231, pp. 59–102, 2016.