Termodinamička svojstva dvokomponentnih smeša terpena i 1-propanola u intervalu temperature (288,15 – 323,15) K i na atmosferskom pritisku
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Aug 3, 2023
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Najzastupljenija klasa hemijskih jedinjenja prisutna u esencijalnim uljima jesu terpeni. Smatraju se zelenim rastvaračima, a potiču iz prirodnih izvora poput biljaka, citrusnog voća, ali i lišća drveća ili šišarki. Pronalaze veliku komercijalnu upotrebu u granama prehrambene industrije, kao prirodne arome i dodaci hrani, pored čega su veoma zastupljeni u farmaceutskoj i kozmetičkoj industriji. U cilju proučavanja termodinamičkih svojstava smeša terpena (α-pinen, p-cimen i linalool) sa 1-propanolom, eksperimentalno su određene gustine i viskoznosti za navedene smeše. Eksperimentalna merenja rađena su u opsegu temperatura od 288,15 do 323,15 K na atmosferskom pritisku, za ceo opseg udela. Na osnovu eksperimentalno dobijenih rezultata za gustine i viskoznosti izračunate su vrednosti dopunske molarne zapremine, kao i vrednosti promene viskoznosti pri mešanju. Izmerene veličine (gustina i viskoznost) korelisane su korišćenjem Heric-Brewer-Jouyban-Acree modela, dok je za korelisanje dopunskih veličina (dopunska molarna zapremina i promena viskoznosti) korišćen Redlich-Kister polinom. Svi eksperimentalno dobijeni podaci i njihove izvedene veličine korišćene su za analizu neidealnog ponašanja odabranih smeša. Heric-Brewer-Jouyban-Acree model je uspešno korelisao eksperimentalne vrednosti za sva tri binarna sistema u celom temperaturnom opsegu i na atmosferskom pritisku, dok je Redlich-Kister uspešno korelisao izvedene veličine.
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Kako citirati
GROZDANIĆ, Nikola D. et al.
Termodinamička svojstva dvokomponentnih smeša terpena i 1-propanola u intervalu temperature (288,15 – 323,15) K i na atmosferskom pritisku.
Zbornik Međunarodnog kongresa o procesnoj industriji – Procesing, [S.l.], v. 36, n. 1, p. 219, aug. 2023.
Dostupno na: <https://izdanja.smeits.rs/index.php/ptk/article/view/6914>. Datum pristupa: 24 mar. 2025
Sekcija
Procesne tehnologije
Reference
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[19] Florido M, Andrade G, Capellini C, Carvalho H, Aracava K, Koshima C, Rodrigues C, Goncalves B. Viscosities and densities of systems involved in the deterpenation of essential oils by liquid-liquid extraction: New UNIFAC-VISCO parameters. J. Chem. Thermodyn. 2014; 72: 152-160.
[20] Comelli F, Francesconi R, Castellari C. Densities, Viscosities, and Excess Molar Enthalpies of Binary Mixtures Containing Essential Oils at (298.15 and 313.15) K. The (S)-(−)-Limonene + Cineole, (S)-(−)-Limonene + Linalool, and Cineole + Linalool Systems. J. Chem. Eng. Data. 2001; 46: 868–872.
[21] Comelli F, Ottani S, Francesconi R, Castellari C. Densities, Viscosities, and Refractive Indices of Binary Mixtures Containing n-Hexane + Components of Pine resins and Essential Oils at 298.15 K. J. Chem. Eng. Data. 2002; 47: 93-97.
[22] Vercher E, Orchilles V, Miguel P, Martinez-Andreu A. Volumetric and Ultrasonic Studies of 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate Ionic Liquid with Methanol, Ethanol, 1-Propanol, and Water at Several Temperatures. J. Chem. Eng. Data. 2007; 52: 1468-1482.
[23] Pal A,Kumar A. Viscosity of 1-Propanol + Ethylene Glycol Dimethyl, + Diethylene Glycol Dimethyl, + Triethylene Glycol Dimethyl, and + Tetraethylene Glycol Dimethyl Ethers at 288.15, 298.15 and 308.15 K. Indian J.Chem.A. 2003; 42: 2708-16.
[24] Yang C, Lai H, Liu Z, Ma P. Density and Viscosity of Binary Mixtures of Diethyl Carbonate with Alcohols at (293.15 to 363.15) K and Predictive Results by UNIFAC-VISCO Group Contribution Method. J. Chem. Eng. Data. 2006; 51: 1345-1351.
[25] Rodriguez A, Canosa J, Dominguez A, Tojo J. Dynamic viscosities of diethyl carbonate with linear and secondary alcohols at several temperatures. J. Chem. Eng. Data. 2004; 49: 157-162.
[26] Redlich O, Kister T. Algebraic representation of thermodynamic properties and the classification of solutions. Industrial & Engineering Chemistry. 1948; 40(2): 345-348.
[27] Jouyban A, Khoubnasabjafari M, Vaez-Gharamaleki Z, Fekari Z, Eugene Jr W. Calculation of the viscosity of binary liquids at various temperatures using Jouyban–Acree model. Chemical and Pharmaceutical Bulletin. 2005; 53(5): 519-523.
[28] Wan Normazlan D, Sairi A, Alias Y, Udaiyappan F, Jouyban A, Khoubnasabjafari M. Composition and temperature dependence of density, surface tension, and viscosity of EMIM DEP/MMIM DMP+ water+ 1-propanol/2-propanol ternary mixtures and their mathematical representation using the Jouyban–acree model. J. Chem. Eng. Data. 2014; 59(8): 2337-2348.
[29] Saleh A, Habibullah M, Ahmed S, Uddin A, Uddin H, Khan M, Excess Molar Volumes and Viscosities of Some Alkanols with Cumene. Phys. Chem. Liq. 2006; 44: 31-43.
[2] Rodriguez-Garcia A, Hosseini S, Martinez-Chapa S, Cordell A, Multi-target activities of selected alkaloids and terpenoids. Mini-Reviews in Organic Chemistry. 2017; 14(4): 272-279.
[3] Papada E, Gioxari A, Brieudes V, Amerikanou C, Halabalaki M, Skaltsounis L, Kaliora C. Bioavailability of terpenes and postprandial effect on human antioxidant potential. An open‐label study in healthy subjects. Molecular Nutrition & Food Research. 2018; 62(3): 1700751.
[4] Allenspach M, Steuer C. α-Pinene: A never-ending story. Phytochemistry. 2021; 190: 112857.
[5] Jung K, Lee Y, Choi W, Jae J, Ha M, Suh J, Lee Y. Production of high-energy-density fuels by catalytic β-pinene dimerization: effects of the catalyst surface acidity and pore width on selective dimer production. Energy Conversion and Management. 2016; 116: 72-79.
[6] Oswald P, Whitside R, Schäffer J, Köhler M. An experimental flow reactor study of the combustion kinetics of terpenoid jet fuel compounds: Farnesane, p-menthane and p-cymene. Fuel. 2017; 187: 43-50.
[7] Balahbib A, El Omari N, Hachlafi E, Lakhdar F, El Menyiy N, Salhi N, Bouyahya A. Health beneficial and pharmacological properties of p-cymene. Food and Chemical Toxicology. 2021; 153: 112259.
[8] Marchese A, Arciola R, Barbieri R, Silva S, Nabavi F, Tsetegho Sokeng J., Nabavi M. Update on monoterpenes as antimicrobial agents: A particular focus on p-cymene. Materials. 2017; 10(8): 947.
[9] Cheng H, Lin Y, Yeh F, Cheng S, Chang T. Potential source of S-(+)-linalool from Cinnamomum osmophloeum ct. linalool leaf: essential oil profile and enantiomeric purity. Journal of agricultural and food chemistry. 2012; 60(31): 7623-7628.
[10] Hussain I, Anwar F, Sherazi H, Przybylski R. Chemical composition, antioxidant and antimicrobial activities of basil (Ocimum basilicum) essential oils depends on seasonal variations. Food chemistry. 2008; 108(3): 986-995.
[11] Bakkali F, Averbeck S, Averbeck D, Idaomar M. Biological effects of essential oils–a review. Food and chemical toxicology. 2008; 46(2): 446-475.
[12] Meylemans A, Quintana L, Goldsmith R, Harvey G. Solvent‐free conversion of linalool to methylcyclopentadiene dimers: a route to renewable high‐density fuels. ChemSusChem. 2011; 4(4): 465-469.
[13] Radovic I, Grozdanic N, Djordjevic B, Serbanovic S, Kijevcanin M. Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models, Journal of the Serbian Chemical Society. 2017; 82: 1379-1390.
[14] Grozdanic N, Radovic I, Knezevic-Stevanovic A, Kijevcanin M. Volumetric properties of binary mixtures of tetrahydrofuran, dimethyl adipate, 1-butanol and 2-butanol from (288.15 to 323.15) K and modeling by Prigogine-Flory-Patterson (PFP) and Extended Real Association Solution (ERAS) models. Journal of Molecular Liquids. 2021; 340: 117313.
[15] Ilic-Pajic J, Radovic I, Grozdanic N, Stajic-Trosic J, Kijevcanin M. Volumetric and thermodynamic properties of binary mixtures of p-cymene with α-pinene, limonene and citral at atmospheric pressure and temperatures up to 323.15 K. Journal of Molecular Liquids. 2021; 344: 117486.
[16] Ribeiro A, Bernardo-Gil G. Densities and refractive indices of components of pine resin. J. Chem. Eng. Data. 1990; 35: 204-206.
[17] Liao D-K, Meng X-L, Tong Z-F, Zheng D-X, Peng D-Y, Lu B. Excess Molar Enthalpies of p-cymene + α-Pinene + β-Pinene at (298.15, 308.15 and 318.15) K and at Atmospheric Pressure. J. Chem. Eng. Data. 2007; 52: 808-811.
[18] Clara R, Gomez Marigliano A, Solimo H. Density, Viscosity, and Refractive Index in the Range (283.15 to 353.15) K and Vapor Pressure of r-Pinene, d-Limonene, (()-Linalool, and Citral Over the Pressure Range 1.0 kPa Atmospheric Pressure. J. Chem. Eng. Data. 2009; 54: 1087–1090.
[19] Florido M, Andrade G, Capellini C, Carvalho H, Aracava K, Koshima C, Rodrigues C, Goncalves B. Viscosities and densities of systems involved in the deterpenation of essential oils by liquid-liquid extraction: New UNIFAC-VISCO parameters. J. Chem. Thermodyn. 2014; 72: 152-160.
[20] Comelli F, Francesconi R, Castellari C. Densities, Viscosities, and Excess Molar Enthalpies of Binary Mixtures Containing Essential Oils at (298.15 and 313.15) K. The (S)-(−)-Limonene + Cineole, (S)-(−)-Limonene + Linalool, and Cineole + Linalool Systems. J. Chem. Eng. Data. 2001; 46: 868–872.
[21] Comelli F, Ottani S, Francesconi R, Castellari C. Densities, Viscosities, and Refractive Indices of Binary Mixtures Containing n-Hexane + Components of Pine resins and Essential Oils at 298.15 K. J. Chem. Eng. Data. 2002; 47: 93-97.
[22] Vercher E, Orchilles V, Miguel P, Martinez-Andreu A. Volumetric and Ultrasonic Studies of 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate Ionic Liquid with Methanol, Ethanol, 1-Propanol, and Water at Several Temperatures. J. Chem. Eng. Data. 2007; 52: 1468-1482.
[23] Pal A,Kumar A. Viscosity of 1-Propanol + Ethylene Glycol Dimethyl, + Diethylene Glycol Dimethyl, + Triethylene Glycol Dimethyl, and + Tetraethylene Glycol Dimethyl Ethers at 288.15, 298.15 and 308.15 K. Indian J.Chem.A. 2003; 42: 2708-16.
[24] Yang C, Lai H, Liu Z, Ma P. Density and Viscosity of Binary Mixtures of Diethyl Carbonate with Alcohols at (293.15 to 363.15) K and Predictive Results by UNIFAC-VISCO Group Contribution Method. J. Chem. Eng. Data. 2006; 51: 1345-1351.
[25] Rodriguez A, Canosa J, Dominguez A, Tojo J. Dynamic viscosities of diethyl carbonate with linear and secondary alcohols at several temperatures. J. Chem. Eng. Data. 2004; 49: 157-162.
[26] Redlich O, Kister T. Algebraic representation of thermodynamic properties and the classification of solutions. Industrial & Engineering Chemistry. 1948; 40(2): 345-348.
[27] Jouyban A, Khoubnasabjafari M, Vaez-Gharamaleki Z, Fekari Z, Eugene Jr W. Calculation of the viscosity of binary liquids at various temperatures using Jouyban–Acree model. Chemical and Pharmaceutical Bulletin. 2005; 53(5): 519-523.
[28] Wan Normazlan D, Sairi A, Alias Y, Udaiyappan F, Jouyban A, Khoubnasabjafari M. Composition and temperature dependence of density, surface tension, and viscosity of EMIM DEP/MMIM DMP+ water+ 1-propanol/2-propanol ternary mixtures and their mathematical representation using the Jouyban–acree model. J. Chem. Eng. Data. 2014; 59(8): 2337-2348.
[29] Saleh A, Habibullah M, Ahmed S, Uddin A, Uddin H, Khan M, Excess Molar Volumes and Viscosities of Some Alkanols with Cumene. Phys. Chem. Liq. 2006; 44: 31-43.